Brewsters law: $\tan\theta_B = n$
$$\tan\theta_B = \sqrt{3} \implies \theta_B = \tan^{-1}(\sqrt{3}) = 60°$$At $\theta_B = 60°$: reflected ray is completely plane polarised
Reflected and refracted rays are perpendicular: $\theta_r = 90° - 60° = 30°$
Light is a transverse wave — electric field oscillates perpendicular to direction of propagation. Unpolarised light: electric field oscillates in all directions. Plane polarised: oscillates in one plane only. Methods of polarisation: (1) Selective absorption (Polaroids/dichroic crystals). (2) Reflection at Brewster angle. (3) Scattering (blue sky). (4) Double refraction (birefringent crystals like calcite). Malus law: $I = I_0\cos^2\theta$ (intensity after analyser at angle $\theta$ to polariser).
When light reflects off a dielectric surface at Brewster angle $\theta_B$: reflected ray is completely polarised with E-field perpendicular to plane of incidence. $\tan\theta_B = n_2/n_1$ (from medium 1 to medium 2). For air-glass ($n=1.5$): $\theta_B = \tan^{-1}(1.5) = 56.3°$. At Brewster angle: reflected + refracted rays are perpendicular ($\theta_B + \theta_r = 90°$). p-polarisation (parallel) has zero reflection coefficient. Only s-polarisation (perpendicular) reflected.
$I = I_0\cos^2\theta$ where $\theta$ = angle between plane of polarisation and transmission axis of analyser. $\theta=0°$: $I = I_0$ (maximum). $\theta=90°$: $I=0$ (complete extinction). For unpolarised light through polariser: $I = I_0/2$ (average over all $\theta$). Applications: LCD screens (two polaroids with liquid crystal between them). 3D cinema: different polarizations for left and right eyes. Photography: polaroid filter reduces glare (reflected polarised light blocked).
Certain crystals (calcite, quartz) have two different refractive indices. Ordinary ray (o-ray): obeys Snell law, polarised perpendicular to optic axis. Extraordinary ray (e-ray): does not obey Snell law, polarised parallel to optic axis. Two rays travel at different speeds → phase difference → can produce circularly/elliptically polarised light. Quarter-wave plate: path difference $= \lambda/4$ → circular polarisation (from linear). Half-wave plate: path difference $= \lambda/2$ → rotates polarisation by $2\theta$ (where $\theta$ = angle of incidence to optic axis).
Rayleigh scattering: $I \propto 1/\lambda^4$. Blue light scattered more than red → blue sky, red sunset. Scattered light from sky is partially polarised. Maximum polarisation at 90° to Sun direction. Bees and insects use sky polarisation for navigation. Light scattered perpendicular to incident direction is completely polarised (Tyndall effect). Optical activity: some molecules (glucose, fructose) rotate plane of polarised light. Measurement of optical rotation: polarimetry (used to determine sugar concentration).
When light goes from denser to rarer medium at angle $> $ critical angle $\theta_c$: all light reflected. $\sin\theta_c = n_{rarer}/n_{denser} = 1/n$ (air-glass). For glass ($n=1.5$): $\theta_c = 41.8°$. Applications: optical fibres (light trapped by TIR, bandwidth $>$ 1 THz), diamonds (cut to maximise TIR → brilliance, critical angle $24.4°$), mirage (hot air = rarer medium), prism binoculars (two TIR prisms fold path). Frustrated TIR: if two glass surfaces brought close together, light tunnels through the gap (evanescent wave).
Youngs double slit: fringe width $\beta = \lambda D/d$ where $D$ = screen distance, $d$ = slit separation. Bright fringes at path difference $= m\lambda$. Dark at $(2m+1)\lambda/2$. Coherent sources required (stable phase relationship). Thin film interference: $2nt\cos r = m\lambda$ (for dark fringes, with phase reversal). Anti-reflection coating: $t = \lambda/(4n)$. Newton rings: circular interference fringes. Radius of $m$th ring: $r_m = \sqrt{m\lambda R}$ where $R$ = radius of curvature of lens.
Single slit: first minimum at $\sin\theta = \lambda/a$ (where $a$ = slit width). Central maximum width $= 2\lambda D/a$. Diffraction grating: $d\sin\theta = m\lambda$. Resolving power $= mN$ ($N$ = number of slits). Rayleigh criterion: just resolved when central max of one falls on first min of other. $\theta_{min} = 1.22\lambda/D$ for circular aperture. Telescope resolving power: $D/1.22\lambda$ (larger mirror/lens = better resolution). Bragg diffraction: $2d\sin\theta = n\lambda$ (X-rays by crystals). Used to determine crystal structures.