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PhysicsKinetic Theory of Gases

Two gases A and B have the same temperature. Gas A has molecules with diameter $d$ and gas B has diameter $2d$. If number density of B is twice that of A ($n_B = 2n_A$), the ratio of mean free paths $\lambda_A/\lambda_B$ is:

R
Solution written and verified by Roshan, science educator with 5 years of experience teaching NEET and JEE aspirants. Last reviewed September 2026.
Options
1
4
2
2
3
8
4
1
Correct Answer
8
Solution
1

$\lambda = 1/(\sqrt{2}\pi d^2 n)$; $n_B = 2n_A$, $d_B = 2d_A = 2d$

$\lambda_B = 1/(\sqrt{2}\pi(2d)^2(2n_A)) = 1/(8\sqrt{2}\pi d^2 n_A)$

2

$\lambda_A = 1/(\sqrt{2}\pi d^2 n_A)$

$\lambda_A/\lambda_B = 8$

Answer: 8

Mean free path: $\lambda = 1/(\sqrt{2}\pi d^2 n)$
Gas B: diameter 2d, density 2n → $\lambda_B = \lambda_A/8$ → ratio = 8
Theory: Kinetic Theory of Gases
1. Kinetic Theory of Gases

Assumptions: gas molecules are point masses, no intermolecular forces except during collision, collisions are perfectly elastic, molecules are in random motion. Pressure from kinetic theory: $P = \frac{1}{3}mn\overline{v^2}$. Connects microscopic (molecular motion) to macroscopic (P, T, V).

2. Gas Laws from Kinetic Theory

Boyle\'s law: $PV = $ const at constant $T$ (constant $N\overline{v^2}/3$). Charles\' law: $V \propto T$ at const $P$ ($\overline{v^2} \propto T$). Avogadro\'s law: equal volumes of gases at same $T, P$ contain equal molecules (same $n$, same $\overline{v^2}$ → same $P$). Dalton\'s partial pressures: $P_{total} = \sum P_i$ (no interaction).

3. Transport Phenomena

Mean free path: $\lambda = 1/(\sqrt{2}\pi d^2 n)$. Collision frequency: $f = \sqrt{2}\pi d^2 n\overline{v}$. Mean time between collisions: $\tau = \lambda/\overline{v} = 1/(\sqrt{2}\pi d^2 n\overline{v})$. Thermal conductivity $K \propto \lambda v_{avg} C_v \rho$. Viscosity $\eta \propto \lambda v_{avg} \rho$. Diffusion coefficient $D \propto \lambda v_{avg}$. All decrease with increasing pressure (shorter $\lambda$) and increase with temperature.

4. Equipartition of Energy

Each degree of freedom contributes $\frac{1}{2}k_BT$ to average energy. Monoatomic gas: $f = 3$ (translational), $E = \frac{3}{2}k_BT$, $C_v = \frac{3}{2}R$, $\gamma = 5/3$. Diatomic (room temp): $f = 5$ (3 trans + 2 rot), $E = \frac{5}{2}k_BT$, $C_v = \frac{5}{2}R$, $\gamma = 7/5$. Diatomic (high temp): $f = 7$ (+ 2 vibrational), $C_v = \frac{7}{2}R$, $\gamma = 9/7$.

5. Three Different Molecular Speeds

Kinetic theory defines three speeds and questions frequently ask you to distinguish them. The root mean square speed is $v_{rms} = \sqrt{3RT/M}$, the average speed is $\sqrt{8RT/\pi M}$, and the most probable speed is $\sqrt{2RT/M}$. Their ratio is fixed at $v_{rms} : v_{avg} : v_{mp} = 1.73 : 1.60 : 1.41$, so $v_{rms}$ is always the largest and $v_{mp}$ the smallest. Only $v_{rms}$ relates directly to kinetic energy.

6. Degrees of Freedom and Specific Heats

Each degree of freedom contributes $\frac{1}{2}kT$ of energy per molecule. A monatomic gas has 3 translational degrees, giving $C_v = \frac{3}{2}R$ and $\gamma = 1.67$. A diatomic gas adds 2 rotational degrees, giving $C_v = \frac{5}{2}R$ and $\gamma = 1.40$. At high temperature vibrational modes activate and add 2 more, raising $C_v$ to $\frac{7}{2}R$. In every case $C_p - C_v = R$, which is Mayer's relation and holds for all ideal gases.

7. Mean Free Path

The average distance a molecule travels between collisions is $\lambda = \frac{1}{\sqrt{2}\pi d^2 n}$, where d is the molecular diameter and n the number density. Because n falls as pressure falls, the mean free path grows in a vacuum — which is why a vacuum flask insulates so well, and why the mean free path inside a cathode ray tube is long enough for electrons to cross it without colliding.

Where students lose the mark

Using grams per mole in the speed formula. M must be in kg/mol. Using 32 instead of 0.032 for oxygen changes the answer by a factor of about 32.

Thinking temperature measures speed. It measures average kinetic energy. At the same temperature a heavier molecule moves more slowly, which is exactly why the speeds differ between gases.

Frequently Asked Questions
1. What is mean free path? ⌄
Mean free path $\lambda$ = average distance travelled by a molecule between successive collisions. $\lambda = \frac{1}{\sqrt{2}\pi d^2 n}$ where $d$ = molecular diameter, $n$ = number density. Larger molecules or higher density → shorter mean free path.
2. How does molecular diameter affect mean free path? ⌄
$\lambda \propto 1/d^2$. Doubling diameter reduces $\lambda$ by factor of 4 (larger target = more collisions). $\lambda \propto 1/n$ (more molecules = more collisions).
3. What is average speed at same temperature? ⌄
$v_{rms} = \sqrt{3RT/M}$. At same temperature, $v_{rms} \propto 1/\sqrt{M}$. Lighter molecules move faster. Average KE = $\frac{3}{2}k_BT$ (same for all gases at same temperature, regardless of mass).
4. What are the speed distribution functions? ⌄
Maxwell speed distribution: $f(v) = 4\pi n (m/2\pi k_BT)^{3/2} v^2 e^{-mv^2/2k_BT}$. Most probable speed: $v_p = \sqrt{2k_BT/m}$. Mean speed: $v_{avg} = \sqrt{8k_BT/\pi m}$. RMS speed: $v_{rms} = \sqrt{3k_BT/m}$. Ratio: $v_p : v_{avg} : v_{rms} = 1 : 1.128 : 1.225$.
5. What is the relation between pressure and kinetic theory? ⌄
$P = \frac{1}{3}mn\overline{v^2} = \frac{1}{3}\rho\overline{v^2}$ where $n$ = number density, $m$ = molecular mass. $PV = Nk_BT = nRT$. $\frac{1}{2}m\overline{v^2} = \frac{3}{2}k_BT$ (average KE per molecule). $U = \frac{f}{2}nRT$ (internal energy, $f$ = degrees of freedom).
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