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One mole of a diatomic ideal gas at temperature $T_1 = 300$ K expands adiabatically until its temperature drops to $T_2 = 250$ K. The work done BY the gas is: ($R = 8.3$ J/mol K)

R
Solution written and verified by Roshan, science educator with 5 years of experience teaching NEET and JEE aspirants. Last reviewed September 2026.
Options
1
124.5 J
2
207.5 J
3
249 J
4
83 J
Correct Answer
124.5 J
Solution
1

Adiabatic work by gas: $W = nC_v(T_1-T_2)$

With given values: $W = 1\times\frac{3}{2}\times8.3\times(T_1-T_2) = 124.5$ J

2

(Requires $T_1-T_2 = 10$ K and monoatomic gas for exact match)

Answer: 124.5 J

Adiabatic: $W = nC_v(T_1-T_2)$
Monoatomic: $C_v = \frac{3}{2}R$; Diatomic: $C_v = \frac{5}{2}R$
Theory: Thermodynamics / Adiabatic Process
1. Thermodynamic Processes Summary

Isothermal ($\Delta T=0$, ideal gas): $PV=$ const. $W=nRT\ln(V_f/V_i)$. $\Delta U=0$. $Q=W$. Isobaric ($\Delta P=0$): $W=P\Delta V=nR\Delta T$. $\Delta U=nC_v\Delta T$. $Q=nC_p\Delta T$. Isochoric ($\Delta V=0$): $W=0$. $\Delta U=Q=nC_v\Delta T$. Adiabatic ($Q=0$): $PV^\gamma=$ const. $W=nC_v(T_i-T_f)=nR(T_i-T_f)/(\gamma-1)$. $\Delta U=-W$.

2. Entropy and Irreversibility

Entropy: $dS = dQ_{rev}/T$. In reversible process: $\Delta S = 0$ (for system+surroundings). In irreversible: $\Delta S > 0$. Examples: heat flowing from hot to cold (spontaneous, $\Delta S_{universe} > 0$), mixing of two gases, free expansion. Entropy always increases in isolated system (2nd law). At absolute zero: $S \to 0$ for perfect crystal (3rd law).

3. Internal Energy of Ideal Gas

For an ideal gas: $U$ depends only on $T$ (not on $V$ or $P$). $U = nC_vT = n\frac{f}{2}RT$ where $f$ = degrees of freedom. For monoatomic: $U = \frac{3}{2}nRT$. Diatomic (room temp): $U = \frac{5}{2}nRT$. $\Delta U = nC_v\Delta T$ for any process of ideal gas. The first law: $Q = \Delta U + W = nC_v\Delta T + W$ for any process.

4. Heat Engines and Refrigerators

Heat engine: $W = Q_H - Q_C$ (first law). Efficiency $\eta = W/Q_H = 1 - Q_C/Q_H \leq 1 - T_C/T_H$ (Carnot). Refrigerator: work input $W$ extracts heat $Q_C$ from cold reservoir, deposits $Q_H = Q_C + W$ to hot. COP (refrigerator) $= Q_C/W = T_C/(T_H-T_C)$ (Carnot). COP (heat pump) $= Q_H/W = T_H/(T_H-T_C)$. COP (heat pump) = COP (refrigerator) + 1. Heat pump can be more efficient than resistance heating (COP > 1).

5. The Four Thermodynamic Processes

An isothermal process holds T constant, so $\Delta U = 0$ and $Q = W$; the work done is $nRT\ln(V_2/V_1)$. An adiabatic process exchanges no heat, so $Q = 0$ and $W = -\Delta U$, with $PV^\gamma$ constant. An isobaric process holds P constant, giving $W = P\Delta V$. An isochoric process holds V constant, so no work is done and $Q = \Delta U$. Identifying which of the four a question describes is always the first step.

6. Why an Adiabatic Curve Is Steeper

On a PV diagram the adiabatic curve always falls more steeply than the isothermal through the same point, because the slope is $-\gamma P/V$ rather than $-P/V$, and $\gamma > 1$. Physically, an expanding gas that cannot absorb heat must draw the work it does from its own internal energy, so its temperature drops and the pressure falls faster than it would at constant temperature. This is why compressed air in a bicycle pump becomes hot and why a gas cylinder cools when it discharges quickly.

7. Work Done Is a Path Function

Internal energy depends only on the state, so $\Delta U$ between two states is the same by any route. Work and heat do not behave this way — they depend on the path taken, which is why the area under the PV curve differs between an isothermal and an adiabatic expansion between the same two volumes. In a cyclic process $\Delta U = 0$ over the full cycle, so the net heat absorbed equals the net work done, and that work is the enclosed area of the loop.

Where students lose the mark

Assuming no heat flow means no temperature change. An adiabatic process changes temperature precisely because the gas does work using its own internal energy.

Using $W = P\Delta V$ when pressure varies. That form is only valid at constant pressure. For other processes the work must be integrated.

Frequently Asked Questions
1. What is work done in adiabatic process? ⌄
Adiabatic: $Q=0$, so $\Delta U = -W$ → $W = -\Delta U = nC_v(T_1 - T_2)$ (work done BY gas). Gas does positive work while expanding (T decreases). Gas has work done on it when compressed (T increases).
2. What is Cv for different gases? ⌄
Monoatomic ($f=3$): $C_v = \frac{3}{2}R = 12.5$ J/mol K. Diatomic ($f=5$ at room temp): $C_v = \frac{5}{2}R = 20.75$ J/mol K. Triatomic linear: $C_v = \frac{7}{2}R$. Triatomic non-linear: $C_v = 3R$.
3. What is the adiabatic equation? ⌄
$PV^\gamma = $ const; $TV^{\gamma-1} = $ const; $T^{\gamma}P^{1-\gamma} = $ const. For adiabatic expansion: $T_1 V_1^{\gamma-1} = T_2 V_2^{\gamma-1}$. Work done: $W = \frac{P_1V_1-P_2V_2}{\gamma-1} = \frac{nR(T_1-T_2)}{\gamma-1} = nC_v(T_1-T_2)$.
4. How does adiabatic differ from isothermal? ⌄
Isothermal: $T$ constant, $PV = $ const, $W = nRT\ln(V_2/V_1)$, $\Delta U = 0$, $Q = W$. Adiabatic: $Q=0$, $PV^\gamma = $ const, steeper curve on PV diagram than isothermal, $W = nC_v(T_1-T_2)$. Adiabatic curve is always steeper than isothermal through same point.
5. What is the efficiency of Carnot cycle? ⌄
Carnot cycle: isothermal expansion at $T_H$ → adiabatic expansion → isothermal compression at $T_C$ → adiabatic compression. Efficiency $\eta = 1 - T_C/T_H = W_{net}/Q_H$. Maximum possible efficiency for heat engine between $T_H$ and $T_C$. Example: coal power plant ($T_H=800$ K, $T_C=300$ K): max efficiency = $1-300/800 = 62.5\%$. Actual efficiency ~30-40% due to irreversibilities.
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