$V = \frac{4}{3}\pi R^3$; $\gamma = 3\alpha$
$\Delta V = V\gamma\Delta T = \frac{4}{3}\pi R^3 \times 3\alpha\Delta T = 4\pi R^3\alpha\Delta T$
Answer: $4\pi R^3\alpha\Delta T$
Linear: $\Delta l = l\alpha\Delta T$; $l_T = l_0(1+\alpha\Delta T)$. Area: $\Delta A = 2\alpha A\Delta T$ ($\beta = 2\alpha$). Volume: $\Delta V = 3\alpha V\Delta T$ ($\gamma = 3\alpha$). Typical $\alpha$ values: metals $\sim 10^{-5}$ K$^{-1}$; glass $\sim 9\times10^{-6}$; invar (iron-nickel alloy) $\sim 10^{-6}$ (very low, used in precision instruments). Liquids: only volume expansion, $\gamma_{liquid} \approx 10^{-4}$ to $10^{-3}$ K$^{-1}$, generally larger than solids. Gases: $\gamma_{gas} \approx 1/273$ K$^{-1}$ at 0°C (from Charles\' law).
$\frac{dT}{dt} = -k(T - T_s)$ where $T_s$ = surrounding temperature. Solution: $T - T_s = (T_0-T_s)e^{-kt}$. Valid for small temperature difference. Stefan\'s law (general): $\frac{dQ}{dt} = \varepsilon\sigma A(T^4 - T_s^4)$. For small $\Delta T$: reduces to Newton\'s law. Practical application: estimating cooling time of objects, time of death estimation in forensics.
Heat transfer: $Q = mc\Delta T$ (sensible heat); $Q = mL$ (latent heat, phase change). Specific heat of water: $c_w = 4200$ J kg$^{-1}$ K$^{-1}$ (highest of common substances). Principle of calorimetry: heat gained = heat lost (isolated system). Latent heat of fusion (ice): $L_f = 336$ kJ/kg. Latent heat of vaporisation (water): $L_v = 2260$ kJ/kg. $L_v \gg L_f$ (much more energy to convert liquid to gas than solid to liquid).
Conduction: $Q/t = kA\Delta T/l$ (Fourier\'s law). $k$ = thermal conductivity. Good conductors: metals (Cu, Ag, Al). Poor conductors (insulators): wood, glass, air. Convection: transfer by fluid motion. Natural: density difference drives flow (warm fluid rises). Forced: fan or pump. Radiation: $P = \varepsilon\sigma AT^4$ (Stefan-Boltzmann). $\varepsilon$ = emissivity (black body $\varepsilon=1$). Kirchhoff\'s law: good absorber = good emitter at same wavelength. Greenhouse effect: Earth absorbs solar radiation, emits longer IR; greenhouse gases (CO2, CH4) absorb outgoing IR → warming.